![Ni(II) complexes with thioether-functionalized silylamide ligands. Synthesis and crystal structures of [Ni{Me2Si(N-C6H4-2-S-t-Bu)2}], [Ni{Ph2Si(N-C6H4-2-SMe)2}] and [Ni{Ph2Si(N-C6H4-2-SPh)2}] Ni(II) complexes with thioether-functionalized silylamide ligands. Synthesis and crystal structures of [Ni{Me2Si(N-C6H4-2-S-t-Bu)2}], [Ni{Ph2Si(N-C6H4-2-SMe)2}] and [Ni{Ph2Si(N-C6H4-2-SPh)2}]](https://www.degruyter.com/document/doi/10.1515/znb-2018-0263/asset/graphic/j_znb-2018-0263_scheme_001.jpg)
Ni(II) complexes with thioether-functionalized silylamide ligands. Synthesis and crystal structures of [Ni{Me2Si(N-C6H4-2-S-t-Bu)2}], [Ni{Ph2Si(N-C6H4-2-SMe)2}] and [Ni{Ph2Si(N-C6H4-2-SPh)2}]
![NMR and DFT Studies with a Doubly Labelled 15N/6Li S‐Trifluoromethyl Sulfoximine Reveal Why a Directed ortho‐Lithiation Requires an Excess of n‐ BuLi - Hédouin - Angewandte Chemie International Edition - Wiley Online Library NMR and DFT Studies with a Doubly Labelled 15N/6Li S‐Trifluoromethyl Sulfoximine Reveal Why a Directed ortho‐Lithiation Requires an Excess of n‐ BuLi - Hédouin - Angewandte Chemie International Edition - Wiley Online Library](https://onlinelibrary.wiley.com/cms/asset/4aaa0691-61cb-47c0-99a9-f8aa4d87add9/anie202214106-toc-0001-m.jpg)
NMR and DFT Studies with a Doubly Labelled 15N/6Li S‐Trifluoromethyl Sulfoximine Reveal Why a Directed ortho‐Lithiation Requires an Excess of n‐ BuLi - Hédouin - Angewandte Chemie International Edition - Wiley Online Library
![SOLVED: The reaction of 2-butylthiophene with n-butyllithium (n-BuLi), followed by quenching with N,N- dimethylformamide (DMF) , produces 5-butylthiophene-2-carbaldehyde in good yield. 1.n-BuLi; THF 2. DMF 2-butylthiophene 5-butylthiophene-2 ... SOLVED: The reaction of 2-butylthiophene with n-butyllithium (n-BuLi), followed by quenching with N,N- dimethylformamide (DMF) , produces 5-butylthiophene-2-carbaldehyde in good yield. 1.n-BuLi; THF 2. DMF 2-butylthiophene 5-butylthiophene-2 ...](https://cdn.numerade.com/ask_images/048b5b26f2e147e08f13b9b2c718a052.jpg)
SOLVED: The reaction of 2-butylthiophene with n-butyllithium (n-BuLi), followed by quenching with N,N- dimethylformamide (DMF) , produces 5-butylthiophene-2-carbaldehyde in good yield. 1.n-BuLi; THF 2. DMF 2-butylthiophene 5-butylthiophene-2 ...
![Scheme 112. Reagents: i, s-BuLi (2 equiv), TMEDA, Et 2 O, –78ºC; ii, E... | Download Scientific Diagram Scheme 112. Reagents: i, s-BuLi (2 equiv), TMEDA, Et 2 O, –78ºC; ii, E... | Download Scientific Diagram](https://www.researchgate.net/publication/229014398/figure/fig16/AS:393821901869070@1470905866546/Scheme-112-Reagents-i-s-BuLi-2-equiv-TMEDA-Et-2-O-78C-ii-E-PhCH-2-Br-Me-3.png)
Scheme 112. Reagents: i, s-BuLi (2 equiv), TMEDA, Et 2 O, –78ºC; ii, E... | Download Scientific Diagram
![Scheme 86. Reagents: i, t-BuLi (2 equiv), Et 2 O, –78ºC; ii, TMEDA;... | Download Scientific Diagram Scheme 86. Reagents: i, t-BuLi (2 equiv), Et 2 O, –78ºC; ii, TMEDA;... | Download Scientific Diagram](https://www.researchgate.net/profile/Miguel-Yus-2/publication/229014398/figure/fig8/AS:393821901869061@1470905866262/Scheme-86-Reagents-i-t-BuLi-2-equiv-Et-2-O-78C-ii-TMEDA-iii-E-D-2-O-Me-3_Q640.jpg)